A classification of plane and planar 2-trees

We present new functional equations for the species of plane and of planar (in the sense of Harary and Palmer, 1973) 2-trees and some associated pointed species. We then deduce the explicit molecular expansion of these species, i.e a classification of their structures according to their stabilizers. There result explicit formulas in terms of Catalan numbers for their associated generating series, including the asymmetry index series. This work is closely related to the enumeration of polyene hydrocarbons of molecular formula C_nH_n+2.