(15-crown-5)BiI$_3$ as a Building Block for Halogen Bonded Supramolecular Aggregates

Bettina Wagner; Johanna Heine

(15-crown-5)BiI$_3$ as a Building Block for Halogen Bonded Supramolecular Aggregates

Chemical Physics 2020-10-19 v1 Materials Science

Authors: Bettina Wagner , Johanna Heine

Abstract

We present the synthesis and characterization of (15-crown-5)BiI $_3$ (1) and (15-crown-5)BiI $_3$ *0.5TIE (2), a halogen bonded adduct with tetraiodoethylene (TIE), a typical halogen bond donor. Our results show that crown ether complexes of main group metal halides can be employed as halogen bond acceptors for the synthesis of new supramolecular aggregates and highlight the significant interaction between the two building blocks.

Keywords

halogen bond supramolecular aggregate 15-crown-5 bii3 tetraiodoethylene crown ether complex

Cite

@article{arxiv.2010.07984,
  title  = {(15-crown-5)BiI$_3$ as a Building Block for Halogen Bonded Supramolecular Aggregates},
  author = {Bettina Wagner and Johanna Heine},
  journal= {arXiv preprint arXiv:2010.07984},
  year   = {2020}
}

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