Ethanol is conventionally perceived only as a pungent tastant, while the potential sweet properties of ethanol clusters have remained unrecognized. Here we show that ethanol tetramers exhibit a unique time dependent lingering sweetness, distinct from the immediate upupfront sweetness of conventional sweeteners. To objectively verify this phenomenon, we developed an impedance based bionic electronic tongue that monitors changes at a lipid polymer membrane interface. Sensory evaluation revealed increasing ethanol cluster content from 4.83% to 29.53% prolonged sweetness duration from 10s to 25s, whereas sweetness intensity remained low to moderate (1.0-1.7 on a 10 point scale). Using this electronic tongue, we achieved objective discrimination between upfront and lingering sweetness,full band phase angle scanning identified optimal frequencies of 0.933Hz (t=0.171s) for xylitol (fast binding and dissociation) and 0.03Hz (t=5.305s) for ethanol clusters (slow binding and dissociation). Phase angle responses correlated strongly with sensory sweetness duration. In natural aged Chinese Baijiu (1-20 years), low frequency phase angle signals positively correlated with sensory lingering sweetness scores, confirming that ethanol cluster accumulation during aging underpins the sweetness of Baijiu. This work expands the classic AH-B sweetness theory from single molecules to supramolecular clusters and provides an analytical platform for probing the temporal dimension of flavor perception.